大试管回流消解-等离子体发射光谱／质谱法测定植物样品中多元素   总被引：2，自引：1，他引：2  

马生凤温宏利  巩爱华孙德忠 《岩矿测试》2007,26(3):183-187

采用大试管和红外加热的多孔控温消解炉的简单装置消解植物样品，电感耦合等离子体发射光谱／质谱法测定其中的主量和痕量元素，对消解温度、消解时间、消解溶剂、样品取样量等条件进行考察。用植物国家一级标准物质进行前处理及测定，验证方法的可行性，测定值与标准值基本吻合。方法不仅能同时测定B、Ba、Ca、Cd、Cu、K、Mg、Mn、Na、Ni、P、S、Zn、CoSr、Pb、Cr等元素，还适用于Hg、As挥发性元素的消解测定。方法的精密度（RSD，n=10）≤10％。  相似文献   

基于虚功原理的悬索桥隧道式锚碇边坡稳定性分析     

曾钱帮  王思敬 《工程地质学报》2007,15(1):22-32

本文基于虚功原理,结合工程地质勘察资料,在岩层层面和不利结构面组合切割下,由于锚碇工程荷载作用,研究坝陵河大桥西岸隧道式锚碇边坡的整体稳定性。本文的力学分析模型采用多个块体破坏机构的分析方法,假定块体的底面和侧面均达到了极限平衡状态,安全系数可通过功能平衡的虚功原理表达式来求解。功能平衡方程中仅有安全系数一个未知数,条块底部和界面上的法向压力和切向摩擦力并不出现,求解大为简化。  相似文献   

Homogeneity of the Geochemical Reference Material BRP-1 (Paraná Basin Basalt) and Assessment of Minimum Mass     

Aloísio J.B. Cotta  Jacinta Enzweiler  Stephen A. Wilson  Carlos A. Pérez  Antonio J.R. Nardy  João H. Larizzatti 《Geostandards and Geoanalytical Research》2007,31(4):379-393

Reference materials (RM) are required for quantitative analyses and their successful use is associated with the degree of homogeneity, and the traceability and confidence limits of the values established by characterisation. During the production of a RM, the chemical characterisation can only commence after it has been demonstrated that the material has the required level of homogeneity. Here we describe the preparation of BRP-1, a proposed geochemical reference material, and the results of the tests to evaluate its degree of homogeneity between and within bottles. BRP-1 is the first of two geochemical RM being produced by Brazilian institutions in collaboration with the United States Geological Survey (USGS) and the International Association of Geoanalysts (IAG). Two test portions of twenty bottles of BRP-1 were analysed by wavelength dispersive-XRF spectrometry and major, minor and eighteen trace elements were determined. The results show that for most of the investigated elements, the units of BRP-1 were homogeneous at conditions approximately three times more rigorous than those strived for by the test of "sufficient homogeneity". Furthermore, the within bottle homogeneity of BRP-1 was evaluated using small beam (1 mm²) synchrotron radiation XRF spectrometry and, for comparison, the USGS reference materials BCR-2 and GSP-2 were also evaluated. From our data, it has been possible to assign representative minimum masses for some major constituents (1 mg) and for some trace elements (1-13 mg), except Zr in GSP-2, for which test portions of 74 mg are recommended.  相似文献   

Estimation of Block Sizes for Rock Masses with Non-persistent Joints   总被引：2，自引：3，他引：2  

B. H. Kim  M. Cai  P. K. Kaiser  H. S. Yang 《Rock Mechanics and Rock Engineering》2007,40(2):169-192

Summary  Discontinuities or joints in the rock mass have various shapes and sizes. Along with the joint orientation and spacing, the joint persistence, or the relative size of the joint, is one of the most important factors in determining the block sizes of jointed rock masses. Although the importance of joint persistence on the overall rock mass strength has long been identified, the impact of persistence on rock strength is in most current rock mass classification systems underrepresented. If joints are assumed to be persistent, as is the case in most designs, the sizes of the rock blocks tend to be underestimated. This can lead to more removable blocks than actually exist in-situ. In addition, a poor understanding of the rock bridge strength may lead to lower rock mass strengths, and consequently, to excessive expenditure on rock support. In this study, we suggest and verify a method for the determination of the block sizes considering joint persistence. The idea emerges from a quantitative approach to apply the GSI system for rock mass classification, in which the accurate block size is required. There is a need to statistically analyze how the distribution of rock bridges according to the combination of joint orientation, spacing, and persistence will affect the actual size of each individual block. For this purpose, we generate various combinations of joints with different geometric conditions by the orthogonal arrays using the distinct element analysis tools of UDEC and 3DEC. Equivalent block sizes (areas in 2D and volumes in 3D) and their distributions are obtained from the numerical simulation. Correlation analysis is then performed to relate the block sizes predicted by the empirical equation to those obtained from the numerical model simulation. The results support the concept of equivalent block size proposed by Cai et al. (2004, Int. J. Rock Mech. Min. Sci., 41(1), 3–19).  相似文献   

中国优质环保型炼焦煤的评价及资源量等级     

秦云虎  李壮福秦勇 高峰 《中国煤田地质》2007,19(6):21-22

我国炼焦煤资源丰富，但优质炼焦煤一直处于短缺局面。根据全国已有煤质数据分析，从优质（主要考虑挥发分指标）、环保（主要考虑硫分和灰分指标）两个方面结合有害微量元素含量，将炼焦煤划分为四种类型，确定了优质环保型炼焦煤资源的评价步骤，对全国五个赋煤区优质环保型炼焦煤的资源量等级进行了统计分析。  相似文献   

Evolution of the Mesozoic Granites in the Xiong''ershan-Waifangshan Region,Western Henan Province,China,and Its Tectonic Implications          下载免费PDF全文

Franco PIRAJNO 《《地质学报》英文版》2007,81(2)

Based on the new data of isotopic ages and geochemical analyses, three types of Mesozoic granites have been identified for the Xiong'ershan-Waifangshan region in western Henan Province: high-Ba-SrⅠ-type granite emplaced in the early stage (～160 Ma),Ⅰ-type granite in the middle stage (～130 Ma) and anorogenic A-type granite in the late stage (～115 Ma). Geochemical characteristics of the high-Ba-SrⅠ-type granite suggest that it may have been generated from the thickened lower crust by partial melting with primary residues of amphibole and garnet. Gradual increase of negative Eu anomaly and Sr content variations reflect progressive shallowing of the source regions of these granites from the early to late stage. New 40Ar/39Ar plateau ages of the early-stage Wuzhangshan granite (156.0±1.1 Ma, amphibole) and middle-stage Heyu granite (131.8±0.7 Ma, biotite) are indistinguishable from their SHRIMP U-Pb ages previous published, indicating a rapid uplift and erosion in this region. The representative anorogenic A-type granite, Taishanmiao pluton, was emplaced at～115 Ma. The evolution of the granites in this region reveals a tectonic regime change from post-collisional to anorogenic between～160 Ma and～115 Ma. The genesis of the early- and middle-stageⅠ-type granites could be linked to delamination of subducted lithosphere of the Qiniing orogenic belt, while the late-stage A-type granites represent the onset of extension and the end of orogenic process. In fact, along the Qiniing -Dabie-Sulu belt, the Mesozoic granitoids in western Henan, Dabieshan and Jiaodong regions are comparable on the basis of these temporal evolutionary stages and their initial 87Sr/86Sr ratios, which may suggest a similar geodynamic process related to the collision between the North China and Yangtze cratons.  相似文献   

氡测量在成都平原隐伏断裂研究中的初步应用   总被引：1，自引：0，他引：1       下载免费PDF全文

陈召文  马玉孝  阚泽忠  李永昭  葛良全  岳王景  陈思翰 《甘肃地质》2007,16(4):88-92

通过成都平原大邑—竹瓦铺—五珠沱断裂带、双流—成都—德阳断裂带两条NWW向隐伏断裂进行放射性伽玛能谱和氡气测量,对所获得的相关数据进行对比分析,用放射性测量的方法进一步确认和解释了这两条隐伏断裂的存在。  相似文献   

石河子夏季高温过程的环流特征分析     

安冬亮 《沙漠与绿洲气象(新疆气象)》2007,1(5):29-31

应用1994—2003年NCEP逐日再分析资料,对石河子地区10a夏季出现的10次持续性高温天气过程进行了综合分析,总结了石河子地区高温天气的主要环流及相关物理量的特征,提出了石河子地区夏季高温天气的预报模型。  相似文献   

利用水汽总量资料诊断入梅时间的方法   总被引：3，自引：0，他引：3       下载免费PDF全文

曹晓岗丁金才  叶其欣汪君 邱黎华 《应用气象学报》2007,18(6):791-801

梅雨期是江淮流域从春季到夏季一个重要的过渡时期。传统诊断入梅的方法主要根据雨日和温度及副热带高压位置等来确定。由于雨日的不连续, 天气形势的多变, 常会引起诊断入梅日期的分歧。利用长江三角洲地区地基GPS网所反演的连续的大气水汽总量 (GPS/PWV) 资料详细分析了长江三角洲地区2002—2005年入梅情况, 发现GPS/PWV资料可以反映出入梅前后大气中水汽发生显著季节性跳跃的特征, 总结出利用大气中水汽变化特征来诊断入梅时间的方法 (PWV方法)。采用1980—2000年的历史探空资料计算的大气水汽总量 (PWV) 资料, 对该方法进行了检验:21年中有13年的入梅日期与历史上传统方法诊断的入梅日期相吻合; 对两种方法诊断的入梅日期相差较大的3年的入梅情况进行的分析表明, PWV方法诊断出的入梅日比原定入梅日更合理。该方法在2006年入梅诊断的应用也得到验证。  相似文献   

夏季东亚西风急流扰动异常与副热带高压关系研究   总被引：7，自引：1，他引：7       下载免费PDF全文

杨莲梅  张庆云 《应用气象学报》2007,18(4):452-459

利用1979—2003年NCEP/NCAR月平均再分析资料, 探讨夏季 (6—8月) 200 hPa东亚西风急流扰动异常与南亚高压和西太平洋副热带高压的关系。研究指出:夏季200 hPa东亚西风急流扰动动能加强 (减弱), 东亚西风急流位置偏南 (偏北)、强度偏强 (偏弱); 东亚西风急流扰动动能强弱不仅与北半球西风急流强弱和沿急流的定常扰动有关, 而且还与东亚地区高、中、低纬南北向的扰动波列有关, 亚洲地区是北半球中纬度环球带状波列异常最大的区域。夏季200 hPa东亚西风急流扰动动能加强 (减弱), 南亚高压的特征为位置偏东 (偏西)、强度加强 (减弱); 西太平洋副热带高压的特征为位置偏南 (偏北)。东亚环流特别是500 hPa西太平洋副热带高压对东亚西风带扰动异常的响应由高空东亚西风急流南侧的散度场及其对流层中下层热带和副热带地区的垂直速度距平场变化完成。  相似文献